Intergranular stress corrosion cracking igscc of austenitic stainless steels, usually aisi 304 steel, is a serious problem in boiling water reactors bwr. Stress corrosion cracking can proceed in one of two ways. This form of corrosion cracking is caused by a combination of tensile stresses on the material in the presence of corrosive conditions. Intergranular stress corrosion cracking of copper a case study. Stress corrosion cracking scc is the cracking induced from the combined influence. Understanding and avoiding intergranular stress corrosion. Intergranular corrosion igc microstructure of metals and alloys is made up of grains separa ted by grain boundaries intergranular corrosion is a localized attack along the grain bo undaries, or immediately adjacent to grain boundaries, while the bulk of t he grains remain largely unaffected igc is associated. Intergranular stress corrosion cracking igscc is the progressive nucleation and growth of cracks by localized corrosion along the grain boundaries in metals in the presence of stress or strain. This is, of course, a very complex question for a forum like this. Observations of intergranular stress corrosion cracking in. The process of cracking is not strictly a mechanical process, as the corrosivity of the environment strongly affects the fracture mode.
In our previous research, the transgranular stress corrosion cracking behavior of 304 stainless steel in 0. Some examples of stress corrosion cracking in service are described. Fracture mechanicsbased testing was used to quantify the stresscorrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in full. Cepa stress corrosion cracking recommended practices 2nd edition. There are several other processes that can lead to intergranular fracture, or preferential crack propagation at the grain boundaries. Dec 19, 2019 intergranular cracking is a form of corrosive attack that progresses preferentially along grain boundaries. There appears to be no unique mechanism of transgranular stress corrosion cracking, since no single factor is common to all susceptible alloys. Intergranular corrosion igc, also known as intergranular attack iga, is a form of corrosion where the boundaries of crystallites of the material are more susceptible to corrosion than their insides. Intergranular and transgranular stress corrosion cracking of carbon steel in fuelgrade ethanol. An additional document titled addendum on circumferential scc was published in 1998 that specifically addressed the much lesscommon circumferential scc. Probability is discussed in relation to its role of predicting the stress corrosion cracking of cu metals.
A computational model for intergranular stress corrosion. Nickel alloys, stainless steels ss, aluminum alloys and other metallic alloys are susceptible to scc. If stress induces cracking under these conditions, the path is transgranular. Intergranular stress corrosion cracking igscc is defined as cracking that occurs along the grain boundaries of crystallites due to corrosion. What is the major difference between intergranular fracture. The interaction of corrosion fatigue and stresscorrosion. Stress corrosion of austenitic steels is usually transgranular.
Intergranular corrosion is sometimes also called intercrystalline corrosion or interdendritic corrosion. The results indicate that the electrochemical contribution to the scc of cu30au in 0. Intergranular fracture occurs when a crack propagates along the grain boundaries of a material, usually when these grain boundaries are weakened. In general, however, all susceptible alloys are unstable in the environment concerned but are largely protected by a surface film. Figure 44 transgranular cracking in pipeline steel revie 2000. Transgranular, intergranular, and granulated stress corrosion cracks were observed. Stress corrosion cracking odonnell consulting engineers. Is the transgranular stress corrosion cracking is because of chlorides present in the. The competition between intergranular ig and transgranular tg fracture in fcc polycrystalline aggregates with physically representative gb misorientation distributions comprised of random lowangle, random highangle, and coincident site lattice csl gbs has been investigated.
Laboratory simulation with small test specimens indicates. Transgranular, granulated, and intergranular stress corrosion. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. Transgranular stress corrosion cracking of highpressure. Stress corrosion cracking starts from corrosion sites at the material surfaces and progresses into a brittle manner. Though it is easy to identify intergranular cracking, pinpointing the cause is more complex as the mechanisms are more varied, compared to transgranular fracture. Intergranular stress corrosion cracking of core shrouds. Duplex stainless steels possess superior resistance to both transgranular and intergranular stress corrosion cracking. It is associated with the simultaneous presence of a number of factors. In general, however, all susceptible alloys are unstable in the environment concerned but are largely protected by a surface film that is locally destroyed in some way. Commercial titanium can suffer intergranular stress corrosion cracking see stress corrosion cracking in methanolic environments and red fuming nitric acid but otherwise it is immune to failure. Delanty introduction the majority of instances of stress corrosion cracking scc in highpressure gas pipelines has been associated with the propagation of intergranular cracks.
This paper evaluates the resistance to intergranular stress corrosion cracking igscc in the boiling water reactor of several grades and compositions of austenitic stainless steel castings. Many alloys, notably the austenitic stainless steels, exhibit intergranular as well as transgranular stress corrosion cracking scc in ct environments. Intergranular stress corrosion cracking of welded steel twi. Susceptibility to stress corrosion cracking of 254smo ss. Feb 06, 2011 intergranular corrosion igc microstructure of metals and alloys is made up of grains separa ted by grain boundaries intergranular corrosion is a localized attack along the grain bo undaries, or immediately adjacent to grain boundaries, while the bulk of t he grains remain largely unaffected igc is associated.
Intergranular stress corrosion cracking igscc of bwr internal components has been identified as a technical issue of concern by both the nrc staff and the industry. The required tensile stresses may be in the form of directly applied stresses or in the form of residual. Crack propagation, intergranulartransgranular transition, finite. Intergranular stress corrosion cracking in rbmk reactors to assist countries operating rbmk reactors in addressing the issue in austenitic stainless steel 300 mm diameter piping. There are a lot of similarities with the intergranular and transgranular scc mechanisms occurring in fge compared to carbonate solutions. If the sample was simultaneously stressed and dealloyed, the fracture mode was transgranular cleavage. The mechanism of stress corrosion cracking scc of cu30au in 0. Stress corrosion cracking processes associated with chemical dissolution along grain boundaries. What is the major difference between intergranular. The interaction between a propagating intergranular stress corrosion crack and the microstructure has been investigated by insitu three dimensional observations of intergranular stress corrosion cracking, using the id19 xray microtomography beam line at the european synchrotron radiation facility esrf, france 79. Stress corrosion cracking international institute of. Intergranular stress corrosion cracking igscc is stress corrosion cracking where the grain boundaries of a susceptible material are cracked due to stress and an agressive environment. Stress corrosion cracking can be either transgranular or intergranular.
It follows the pattern of grains in the individual lattices of the material. Stress corrosion cracking is not instantaneous, so time is a factor in its occurrence. Crack growth rates are typically relatively rapid, up to 1 mms in the most. Physicallybased critical conditions for ig fracture, due to the formation of. Other problems that have been observed with inconel include wastage, tube denting, pitting, and intergranular attack. Ways of propagation of scc scc can proceed in either of two ways. Characterization of intergranular stress corrosion cracking of 304. At low values of stress, failure occurred by brittle intergranular cracking, and at high values of stress, failure occurred by brittle transgranular cracking. Characterization of intergranular stress corrosion cracking. Crack growth is driven by the inelastic deformation at the sharp crack tip. In the applied stress region where the stress corrosion crackingdominated fracture occurred, the fracture mode for type 304 and 316 steels at 416 and 428 k was transgranular, while that at 408 k was mostly intergranular, in particular at higher applied stresses figure 5. What is intergranular stress corrosion cracking igscc. Sensitization, intergranular attack, stress corrosion. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material.
Abstract many alloys, notably the austenitic stainless steels, exhibit intergranular as well as transgranular stress corrosion cracking scc in c1. Paper presented at corrosion 2007, paper 07094, nashville, tennessee, 1115 march 2007. At high temperatures, the absorbed hydrogen tends to gather in the grain boundaries and stressinduced cracking is then intergranular. A computational model for intergranular stress corrosion cracking thesis by juli an j. In 28,29,30, the tests are performed under prescribed strain rate, in an aggressive environment. Jul 18, 2008 intergranular stress corrosion cracking igscc is the progressive nucleation and growth of cracks by localized corrosion along the grain boundaries in metals in the presence of stress or strain. This paper discuses the stress corrosion cracking observed when slow strain rate tests were run on aisi 304 stainless steel specimens in oxygenated 288 c water. Abstract supermartensitic stainless steels smss, including both lean grades without molybdenum and high grades with 2% molybdenum, have shown sensitivity to intergranular corrosion or stress corrosion cracking igscc in weld hazs during labor. Transgranular, granulated, and intergranular stress. Both intergranular and transgranular stress corrosion cracking are observed. Intergranular cracking is also known as intergranular corrosion, intergranular corrosion cracking, intergranular stress corrosion cracking igscc, intercrystalline corrosion, interdendritic corrosion or intergranular attack. The core shroud is among the list of internals susceptible to igscc. What is the major difference between intergranular fracture and transgranular fracture. Intergranular stress corrosion cracking an overview.
Paper presented at corrosion 2007, paper 07094, nashville, tennessee, 11. Characterization of intergranular stress corrosion. Intergranular stress corrosion cracking transgranular stress corrosion cracking 14. Generally at lower temperature grain boundaries have more strength than the grains i. Stress corrosion cracking scc is a very common failure mechanism characterized by a slow, environmentally induced crack propagation in structural components.
Instances of tgscc have been associated with dilute solutions with ph values in the region of 6. R moli in partial ful llment of the requirements for the degree of doctor of philosophy california institute of technology pasadena, california 2009 defended may 5, 2009. Differentiating between intergranular and transgranular. Timetofailure tests and crackgrowthrate tests are widespread practices for studying the response of various materials undergoing scc. Dec 09, 2017 intergranular stress corrosion cracking igscc is defined as cracking that occurs along the grain boundaries of crystallites due to corrosion. Simulating intergranular stress corrosion cracking in az31. Commercial titanium can suffer intergranular stresscorrosion cracking see stress corrosion cracking in methanolic environments and red fuming nitric acid but otherwise it is immune to failure. The degree of sensitization also determined the tensile properties observed in the specimens after these slow strain rate tensile tests.
Transgranular cracking is a key characteristic of chloride induced stress corrosion cracking in austenitic stainless steels. Simulation of inter and transgranular crack propagation. A specific objective of this work was to predict the performance of alloy casting institute cf3, cf3a, and cf8 castings in nuclear applications. Various methods for the prevention of stress corrosion cracking are discussed. Transgranular stress corrosion cracking of highpressure pipelines in contact with solutions of near neutral ph r. When fracture occurs through grain boundaries it is called as intergranular fracture and when occurs through grains is called transgranular fracture. The stresses required to initiate and propagate cracking are often low and many failures occur due to residual stresses rather than applied stress. This paper reports that the results indicate that the mechanisms of intergranular stress corrosion cracking and transgranular stress corrosion cracking of cu30 au are identical. In the presence of tensile stress, cracking may occur along grain boundaries and this type of corrosion is frequently called intergranular stress corrosion cracking igscc or simply intergranular corrosion cracking. May 22, 2015 intergranular stress corrosion cracking igscc of bwr internal components has been identified as a technical issue of concern by both the nrc staff and the industry. Physicallybased critical conditions for ig fracture, due to the formation of dislocation pileups, and tg. Transgranular stress corrosion cracking tgscc is the same as igscc, but the grain boundaries are not preferentially attacked 1, 2.
Grain boundary control for improved intergranular stress. Sep 18, 2017 fracture mechanicsbased testing was used to quantify the stress corrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in full. Crystal plasticity, stress corrosion cracking, intergranular. Intergranular cracking proceeds along grain boundaries, while. In order to investigate the development of the microcrack. This paper evaluates the resistance to intergranular stresscorrosion cracking igscc in the boiling water reactor of several grades and compositions of austenitic stainless steel castings.
Intergranular and transgranular stress corrosion cracking of cu 30au. In this study, a grain boundary model with threedimensional 3d cohesive elements for analyzing the intergranular stress corrosion cracking igscc on the crystal level in polycrystalline materials is presented. This situation can happen in otherwise corrosion resistant alloys, when the grain. When alloyed with oxygen or aluminum, transgranular stresscorrosion cracking can be induced in laboratory tests in seawater and in many organic liquids containing traces of water. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Stress corrosion cracking scc is a result of synergic interaction of mechanical tension and chemical reaction. Abstract although intergranular stress corrosion cracking igscc of highpressure gas pipelines has been known for more than 20 years, a transgranular form tgscc was detected more recently. Supermartensitic stainless steels smss, including both lean grades without molybdenum and high grades with 2% molybdenum, have shown sensitivity to intergranular corrosion or stress corrosion cracking igscc in weld hazs during laboratory testing in chloride solutions acidified with co 2 at above about 100c. When alloyed with oxygen or aluminum, transgranular stresscorrosion cracking can be induced in laboratory.
Improved resistance to caustic stress corrosion cracking can be given to inconel by heat treating it at 620 o c to 705 o c, depending upon prior solution treating temperature. Mar 18, 2017 when fracture occurs through grain boundaries it is called as intergranular fracture and when occurs through grains is called transgranular fracture. Intergranular cracking is a form of corrosive attack that progresses preferentially along grain boundaries. Why is chloride stress corrosion cracking transgranular. Intergranular stress corrosion cracking in inconel heat exchanger tube with the crack. This form of corrosion cracking is caused by a combination of tensile stresses on the material in. Transgranular stress corrosion cracking an overview. Although intergranular stress corrosion cracking igscc of highpressure gas pipelines has been known for more than 20 years, a transgranular form tgscc was detected more recently.
Transgranular corrosion is a type of localized corrosion which occurs along cracks or faults across the crystals in metals and alloys. Intergranular stress corrosion cracking resistance of. Abstract many alloys, notably the austenitic stainless steels, exhibit intergranular as well as transgranular stress corrosion cracking scc in c1 environments. The mechanism of cracking in both these modes and the conditions under which the transition from trans to intergranular cracking or vice versa occur are topics of much debate and research. When alloyed with oxygen or aluminum, transgranular stress corrosion cracking can be induced in laboratory tests in seawater and in many organic. The mechanism of cracking in both these modes and the conditions under which the transi. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. The objectives are to characterize the grain boundary microstructure and the fracture mechanism of igscc in az31 mg alloy. Understanding and avoiding intergranular stress corrosion cracking of welded supermartensitic stainless steel.
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